Preparation of Fe-Mn/ETS-10 catalyst and its CO-SCR denitrification performance [Fe-Mn/ETS-10催化剂制备及其CO-SCR的脱硝性能]

作者：Fu G.-Y.; He H.-B.^*; Zhang L.; Ma Y.

来源：Chinese Journal of Nonferrous Metals, 2020, 30(11): 2616-2626.

DOI：10.11817/j.ysxb.1004.0609.2020-35899

• Catalytic denitrification
• CO-SCR catalyst property
• ETS-10 Molecular sieve
• Fe-Mn catalyst

Fe-Mn/ETS-10 catalysts with various compositions were synthesized by high temperature solid state reaction. These catalysts were characterized by X-ray diffractometry(XRD), Fourier transform infrared spectroscopy(IR), scanning electron microscopy(SEM) and X-ray photoelectron spectroscopy(XPS). The effect of different amounts of Fe-Mn/ETS-10 on the morphology, composition and the catalytic reduction performance was studied. The results show that Fe-Mn/ETS-10 has good uniformity and dispersion, the morphology and crystal structure of ETS-10 are kept. 5%Fe-1%Mn/ETS-10 has more active sites and higher deNOx performance. The catalysts activity of CO-SCR results show that denitrification rates of 5%Fe-1%Mn/ETS-10 are 80% and 85% at 300℃ and 400℃, respectively. So, it is concluded that an optimal Fe-Mn/ETS-10 catalyst support ratio (5%Fe-1%Mn/ETS-10) enhances the catalytic activity in the selective catalytic reduction reaction.

• 单位
  武汉科技大学; 安徽大学; 中南大学