Bis{1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole-百N3}bis(3,5-dicarboxybenzoato-百2O1,O1∩)nickel(II) octahydrate

作者:Yong Yan Jia; Jing Jing Fan; Xiang Ge Yin; Wen Long Zhao
来源:Acta Crystallographica Section E-Structure Reports Online, 2013, 69(4): m184-m184.
DOI:10.1107/s1600536813003322

摘要

In the title complex, [Ni(C9H5O6)2(C11H10N4)2]﹞8H2O, the NiII ion exhibits site symmetry 2. It has a distorted octahedral coordination defined by two N atoms from two symmetry-related 1-[(1H-benzimidazol-1-yl)methyl]-1H-imidazole ligands and four O atoms from two symmetry-related 3,5-dicarboxybenzoate anions. In the crystal, the complex molecules and solvent water molecules are linked via O〞H...O, O〞H...N and N〞H...O hydrogen bonds, forming a three-dimensional structure. There are also a number of C〞H...O interactions present.

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