Silver(Ⅱ) 5,10,15,20-tetra(ethoxycarbonyl) porphyrin:An unexpected six-coordinate linear assembled structure

作者：Hua-Hua Wang; Hai-Yang Liu; Fan Cheng; Atif Ali; Lei Shi; Xin-Yan Xiao; Chi-Kwong Chang

来源：Chinese Chemical Letters, 2018, 29(09): 1404-1408.

• Porphyrin
• Silver
• Six-coordinated assembly
• Crystal structure
• Hydrogen bond

The crystal structure of silver(Ⅱ) 5,10,15,20-tetra(ethoxycarbonyl)porphyrin(Ag[Ⅱ]TECP) revealed it formed a one-dimensional coordination polymer through weak Ag–O interactions with an unusual sixcoordinated central silver(Ⅱ) atom.

• 单位
  华南理工大学