cis,cis,cis-(Acetato-百2O,O∩)bis[1,2-bis(diphenylphosphanyl)ethane-百2P,P∩]ruthenium(II) 0.75-trifluoromethanesulfonate 0.25-chloride

作者:Joo Figueira; Joo Rodrigues; Arto Valkonen
来源:Acta Crystallographica Section E-Structure Reports Online, 2013, 69(4): m226-m226.
DOI:10.1107/s160053681300737x

摘要

In the title RuII carboxylate compound, [Ru(C2H3O2)(C26H24P2)2](CF3O3S)0.75Cl0.25, the distorted tris-bidentate octahedral stereochemistry about the RuII atom in the complex cation comprises four P-atom donors from two 1,2-bis(diphenylphosphanyl)ethane ligands [Ru〞P = 2.2881 (13)每2.3791 (13) ] and two O-atom donors from the acetate ligand [Ru〞O = 2.191 (3) and 2.202 (3) ]. The disordered counter-anions are located on the same site in the structure in a 3:1 ratio, the expanded formula comprising four complex cations, three trifluoromethanesulfonate anions and one chloride anion, with two such formula units in the unit cell.

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