呋喃甲醛缩二乙撑三胺希夫碱铜配合物的合成及结构(英文)

作者：杜桂香; 王伟; 李珺; 张逢星

来源：无机化学学报, 2005, (06): 938-940+782.

• 呋喃甲醛
• 希夫碱
• 铜配合物
• 晶体结构

A novel copper(Ⅱ) complex CuL(NO3)2 (where L=N,N′-bis(furaldehyde)-diethylenetriamine) was synthesized and characterized by X-ray crystallography analysis. The crystal belongs to monoclinic, space group C2/c with cell parameters a=1.924 0(6) nm, b=0.792 8(3) nm, c=2.504 1(8) nm, β=111.163(5)°, and Z=8. The coordination geometry around Cu(Ⅱ) is a distorted trigonal-bipyramid, and one-dimensional chain is formed through intermolecular hydrogen bonds. CCDC: 255629.

• 单位
  陕西省物理无机化学重点实验室; 西北大学