Synthesis and Photoelectric Properties of Metal-Organic Zeolites Built from TO4 and Organotin

作者：Chen, Guang-Hui; He, Yan-Ping^*; Zhang, Shu-Hua; Liang, Fu-Pei^*; Zhang, Lei^*; Zhang, Jian

来源：Inorganic Chemistry, 2019, 58(19): 12521-12525.

DOI：10.1021/acs.inorgchem.9b01935

• IMIDAZOLATE FRAMEWORKS
• COORDINATION POLYMERS
• CRYSTAL-STRUCTURE
• CHEMISTRY
• DESIGN
• CO2

Herein we report a novel strategy capable of generating a new class of metal-organic zeolite (MOZ) materials. When the MoO4 or WO4 tetrahedra are employed to assemble with triorganotin R-3 Sn fragments, four 3D networks with the zeolite BCT topology and nonzeotype 4-connected topological net (such as lon and dia) have been generated. The photocurrent study results show that these materials have good photoelectric response and high photophysical stability.

• 单位
  中国科学院福建物质结构研究所; 结构化学国家重点实验室; 桂林理工大学