Manganese-Catalyzed Allylation of Quinazolinones with 4-Vinyl-1,3-dioxolan-2-one via C-H Activation [锰催化的碳酸乙烯亚乙酯对喹唑啉酮的C-H烯丙基化]

作者：Li Y.; Li Y.; Dong Y.; Xia C.; Li Y.

来源：Chinese Journal of Organic Chemistry, 2022, 42(3): 847-853.

DOI：10.6023/cjoc202110002

• Allylation
• C-H activation
• Manganese-catalyzed
• Quinazolinones

The ortho-allylation of quinazolinones with 4-vinyl-1,3-dioxolan-2-one via manganese catalysis has been described. A series of allylation products with potential applications have been obtained. This protocol is also highlighted by good compatibility of functional groups and excellent E/Z selectivity. This work broadens the scope of Mn-catalyzed C-C coupling reactions.

• 单位
  羰基合成与选择氧化国家重点实验室; 中国科学院大学