Aquabis(4-chlorobenzoato)-百2O,O∩;百O-bis(pyridine-百N)cobalt(II)

作者：Ya Li Chen; Chun E Zhang; Peng Fei; Chao Deng

来源：Acta Crystallographica Section E-Structure Reports Online, 2013, 69(4): m210-m210.

DOI：10.1107/s1600536813006752

In the title compound, [Co(C7H4ClO2)2(C5H5N)2(H2O)], the CoII atom is six-coordinated by three O atoms from a bidentate and a monodentate 4-chlorobenzoate ligand, two N atoms from two pyridine ligands and a water O atom, giving a distorted octahedral geometry. In the crystal, the complex molecules are connected by O〞H...O hydrogen bonds and 羽每羽 interactions between the benzene rings [centroid每centroid distance = 3.8924 (17) ] into a chain along [010]. Between adjacent chains, 羽每羽 interactions occur between the pyridine rings [centroid每centroid distance = 3.898 (2) ], giving an overall two-dimensional architecture.