A Copper(Ⅱ)-cadmium(Ⅱ) Heterometallic Hexanuclear Complex:[Cd_4Cu_2(pdc)_4(H_2O)_(14)](H_3pdc=3,5-Pyrazoledicarboxylic Acid)

作者：周馨慧; 银秀菊

来源：结构化学, 2011, 30(02): 180-185.

DOI：10.14102/j.cnki.0254-5861.2011.02.010

• 3
• 5-pyrazoledicarboxylic acid
• heterometallic
• complex hexanuclear
• copper(Ⅱ)-cadmium(Ⅱ) 3
• 5-pyrazoledicarboxylic acid
• heterometallic
• complex hexanuclear
• copper(Ⅱ)-cadmium(Ⅱ)

The title complex 1,[Cd 4 Cu 2 (pdc) 4 (H 2 O) 14 ] (H 3 pdc=3,5-pyrazoledicarboxylic acid),has been solvothermally synthesized and structurally characterized by single-crystal X-ray diffraction.Complex 1 crystallizes in triclinic,space group P1 with a=0.67235(10),b=1.27935(18),c=1.28569(17) nm,α=11...

• 单位
  现代配位化学国家重点实验室; 南京邮电大学; 南京大学