ChemInform Abstract: In situ Formed Bifunctional Primary Amine‐Imine Catalyst: Application to the Construction of Chiral Tertiary Alcohols Through Asymmetric Aldol‐Type Reaction.

作者：Zhijie Mao; Xi Zhu; Aijun Lin; Weipeng Li; Yan Shi; Haibin Mao; Chengjian Zhu; Yixiang Cheng

来源：ChemInform, 2013, (50): no-no.

DOI：10.1002/chin.201350079

• hydroxycarboxylic acids (ether carboxylic acids) a
• indole derivatives
• isoindole derivatives
• C-C bond formation
• catalysis
• phase-transfer catalysis
• diastereoselective syntheses
• enantioselective syn

Abstract The asymmetric aldol‐type reaction of cyclic ketones with β,γ‐unsaturated α‐keto esters and isatins is developed using chiral bisimines as precatalysts.

• 单位
  南京大学