(Pyridine-2-aldoximato-百2N,N∩)bis[2-(pyridin-2-yl)phenyl-百2C1,N]iridium(III)

作者:Satyanarayan Pal; Bimal Chandra Singh
来源:Acta Crystallographica Section E-Structure Reports Online, 2013, 69(3): m159-m159.
DOI:10.1107/s1600536813004297

摘要

In the title complex, [Ir(C11H8N)2(C6H5N2O)], the octahedrally coordinated IrIII atom is bonded to two 2-(pyridin-2-yl)phenyl ligands, through two phenyl C and two pydidine N atoms, and to one pyridine-2-aldoxime ligand through a pyridine N and an oxime N atom. The oxime O atom of the aldoxime unit forms intermolecular C〞H...O hydrogen bonds, which result in a two-dimensional hydrogen-bonded polymeric network parallel to (100). C〞H...羽 interactions are also observed.