摘要

Two Mo/S complexes:K_6[Mo_2O_2S_2(C_2O_4)_2(ClPO_3)_2]·H_2O(1)andK_6[Mo_2O_3S(C_2O_4)_2(ClPO_3)_2]·3H_2O(2)containing oxalate ligand were prepared by the reaction of(NH_4)_2MoS_4 and potassiu oxalate with adding a small amount of H_3PO_4 to adjust the value of pH in system of methanol and water unde...