N-芳基(烷基)-N′-芳基(烷基)-N″-(葡萄糖基硫代亚脲基)膦酰三胺的合成

作者：解正峰; 曹玲华

来源：化学研究与应用, 2005, (02): 245-248.

• 葡萄糖基异硫氰酸酯
• 膦酰二氨基肼
• 膦酰三胺
• 合成 glucosyl isothiocyanate
• N-substituted phosphoramide hydrazide
• phosphorictriamide
• synthesis

N-substituted phosphoramidic chloride was obtained from the reaction of amines with POCl_3,then hydrazinolyzation gave N-substituted phosphoramidohydrazide(2a-2g).Refluxing of 2 with glucosyl isothiocyanate(1)in CHCl_3 gave corresponding N,N′-substituted-N″-(2,3,4,6-tetra-O-acetylglucosylthioureylen...