Formation of Size‐Controllable Tetragonal Nanoprisms by Crystallization‐Directed Ionic Self‐Assembly of Anionic Porphyrin and PEO‐Containing Triblock Cationic Copolymer (Small 30/2023)

作者：Hongjun Jin; Ziyan Wu; Weilin Lin; Yinye Chen; Jingran Zhang; Ruyi Zheng; Haibing Wei; Qinghua Chen; Qingrong Qian; Jianbin Huang; Jie Zhang; Yun Yan

来源：Small, 2023, 19(30).

• anisotropic nanostructures
• crystallization
• ionic self‐assembly
• size control
• triblock copolymers

Anisotropic Nanostructures(#br)In article number 2300688, Yun Yan, Haibing Wei, Qingrong Qian, Jie Zhang, and co‐workers report an exquisite crystallization‐directed ionic self‐assembly (CDISA) to build size‐controllable anisotropic nanostructures via a hierarchical self‐assembly process, involving a requisite aqueous pre‐assembly to micelles and a subsequent evaporation‐induced self‐assembly to nanoprisms. The formation of anisotropic nanostructures derives from the crystalline polyethylene oxide (PEO) segments which endow ionic system with self‐assembling orientation. Length and width of the obtained nanoprisms can be facilely tuned by simply varying the initial concentration of the micellar solution.

• 单位
  合肥工业大学; 北京大学