A study on the composition and structure of cyclic sulfoxide derivative palladium(Ⅱ) complex

作者：Wu Songping; GU Guobang; Meng Shuyuan

来源：稀有金属(英文版), 2004, 23(4): 368-372.

• solvent extraction
• cyclic sulfoxide
• palladium
• complex

The composition and structure of cyclic sulfoxide derivative Pd(Ⅱ) complex were investigated. The coordinated number was studied with slope method. The coordination number is 2 in lower acidity, but it is 3 in higher acidity. Four methods, UV (ultraviolet) spectra, FrIR (Fourier transform infrared) spectra, 1H-NMR (nuclear magnetic resonance)spectra, and 13C-NMR spectra, were used to determine the coordinated atom in complex. Pd is coordinated with O and S atom in S=O group in lower acidity media. The conversion of coordination bond appears with an increasing time. Pd is coordinated with S atom in S=O group in higher acidity media, and inter-ligand-transfer reaction occurs.

• 单位
  华南理工大学