ChemInform Abstract: Rh(I)‐Catalyzed Insertion of Allenes into C—C Bonds of Benzocyclobutenols.

作者：Chunliang Zhao; Li‐Chuan Liu; Jing Wang; Chenran Jiang; Qing‐Wei Zhang; Wei He

来源：ChemInform, 2016, 47(22).

DOI：10.1002/chin.201622102

• hydrogenated naphthalene derivatives
• ring expansion
• catalysis, phase‐transfer catalysis
• diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism)

The site‐ and diastereoselective reaction offers an efficient access to various alkylidene tetralins with two adjacent stereocenters.