科研之友
微信
新浪微博
Facebook
分享链接
摘要
The title compound, C54H69N9O3﹞CHCl3﹞C2H5OH, was prepared by a threefold nucleophilic substitution of p-neomenthyloxyphenyltetrazole on cyanuric chloride followed by threefold cycloelimination of nitrogen and ring closure. The central tristriazolotriazine is roughly planar with a maximum deviation of 0.089 (7) but the adjacent benzene rings are twisted out of this plane. N〞C〞C〞C torsion angles of 80.2 (9), 159.3 (7) and 50.6 (10)～ destroy the formal C3 symmetry. Cavities are found between the phenoxy residues: one is occupied by a chloroform molecule, another by ethanol forming a hydrogen bond to a triazole ring while two isopropyl groups point into the third void. One methyl group and the chlorofrm molecule are disorderd and were refined using a split model.
