catena-Poly[[bis(2-chloropyrazine-百N4)cadmium]-di-米-thiocyanato-百2N:S;百2S:N]

作者:Susanne Whlert; Inke Jess; Christian Nther
来源:Acta Crystallographica Section E-Structure Reports Online, 2013, 69(4): m195-m195.
DOI:10.1107/s1600536813006338

摘要

Reaction of cadmium thiocyanate with 2-chloropyrazine leads to the polymeric title compound, [Cd(NCS)2(C4H3ClN2)2]n. The CdII cation, which is located on a center of inversion, is coordinated by two N-bonded and two S-bonded thiocyanate anions and by two N-bonded 2-chloropyrazine ligands within a slightly distorted octahedron. The CdII cations are linked into chains along the a axis by bridging thiocyanate anions.