Hydrogen‐Generating Ru/Pt Bimetallic Photocatalysts Based on Phenyl‐Phenanthroline Peripheral Ligands

作者：Laura O'Reilly; Dr Qing Pan; Dr Nivedita Das; Dr Kasper Wenderich; Jeroen P Korterik; Prof Johannes G Vos; Dr Mary T Pryce; Dr Annemarie Huijser

来源：ChemPhysChem, 2018, 19(22): 3084-3091.

DOI：10.1002/cphc.201800658

• Electron storage
• Excited-state equilibrium
• Inter-ligand internal conversion
• Ru/Pt photocatalysts
• Ultrafast photodynamics

Abstract(#br)Recent studies on hydrogen‐generating supramolecular bimetallic photocatalysts indicate a more important role of the peripheral ligands than expected, motivating us to design a Ru/Pt complex with 4,7‐diphenyl‐1,10‐phenanthroline peripheral ligands. Photoinduced intra‐ and inter‐ligand i...