Bis(diethylamido-百N)(diethylamine-百N)bis(2,6-diisopropylphenylamido-百N)zirconium(IV)

作者:Mateusz Zauliczny; Rafa Grubba; ukasz Ponikiewski; Jerzy Pikies
来源:Acta Crystallographica Section E-Structure Reports Online, 2013, 69(2): m72-m72.
DOI:10.1107/s160053681205115x

摘要

In the title compound, [Zr(C12H18N)2(C4H10N)2(C4H11N)] or [Zr(HNC6H3iPr2)2(NEt2)2(HNEt2)], which was obtained by the reaction of Zr(NEt)4 with iPr2C6H3NH2, the ZrIV atom is in a trigonal每bipiramidal geometry in which the N atoms from two iPr2C6H3NH and one NEt2 ligand occupy the equatorial positions, and the N atoms of an NEt2 and an Et2NH ligand occupy the apical positions. An intramolecular N〞H...N contact occurs. There are two independent molecules in the asymmetric unit.