Preparation of environment‐friendly hydrophilic rubber from natural rubber grafted with sodium acrylate by reactive melt mixing

作者：Nuinu Pranee; Srichan Sansanee; Ngamlerd Anuchit; Wichian Chamai****; Prasertsri Sarawut; Saengsuwan Sayant; Hinchiranan Napida; Vudjung Chaiwute

来源：Polymer Engineering and Science, 2022, 62(6).

DOI：10.1002/PEN.25968

• hydrophilic
• natural rubber
• reactive melt mixing
• sodium acrylate

In this research, we present an easy way to prepare environment‐friendly hydrophilic rubbers derived from natural rubber (NR) grafted with sodium acrylate (NaAA) through reactive blending using an internal mixer operated at a rotor speed of 80?rpm and 150°C. The key parameters affecting the grafting efficiency of NR‐g‐NaAA were investigated in terms of the fill factor (FF) of the chamber, mixing time, and NaAA content. Lastly, the grafted sample (with a suitable grafting efficiency) was crosslinked using peroxide curing to produce X(NR‐g‐NaAA) as a hydrophilic NR sample. Results showed that grafting efficiency of the NR‐g‐NaAA samples tended to decrease with increasing FF and NaAA contents owing to the higher chain‐scission reaction rather than the free‐radical generation on the NR molecules in the mastication step, while the optimal mixing time was only 4?min. The remarkable improvement in the hydrophilicity of NR by grafting with NaAA was established via the presence of C?=?O vibration of the ionized carboxylate group (–COO?) of NaAA located at 1559?cm?1. Increasing the grafting efficiency up to 69% resulted in a marked decrease in the water contact angle from 103° to 72° and enhanced the water swelling of the X(NR‐g‐NaAA) sample.(#br)Preparation of natural rubber grafted with sodium acrylate by reactive melt mixing.