(Benzyl isocyanide-百C1)chlorido(2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl-百2C1,N)palladium(II)

作者:Ana C Mafud; Milene A R Oliviera; Maria T P Gambardella
来源:Acta Crystallographica Section E-Structure Reports Online, 2013, 69(1): m36-m36.
DOI:10.1107/s1600536812049768

摘要

In the title compound, [Pd(C11H13ClN)Cl(C8H7N)], which crystallized in the chiral space group P212121, the PdII atom is coordinated by two C atoms, a Csp2 atom of the 2-chloro-3-dimethylamino-1-phenylprop-1-en-1-yl ligand and a Csp atom from the benzyl isocyanide ligand, as well as an N atom of the ligand and a Cl atom, in a square-planar geometry. In the complex, there is a short C〞H...Cl hydrogen bond and a C〞H...羽 interaction. In the crystal, molecules are linked via C〞H...Cl hydrogen bonds, forming chains along the a-axis direction.

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