手性1,4-二胺构建的双核铜[2+2]席夫碱大环化合物:制备和催化研究(英文)

作者：诸海滨; 沈宏; 李根喜; 苟少华

来源：无机化学学报, 2006, (07): 1345-1348.

• 双核铜(Ⅱ)
• 大环席夫碱
• 1
• 4-二胺
• 不对称催化 dinuclear copper(Ⅱ)
• macrocyclic Schiff base
• 1
• 4-diamines
• asymmetric catalysis

Dinuclear copper(Ⅱ) complexes of [2+2] macrocyclic Schiff bases have been prepared from chiral 1,4-diamines using sodium ions as template. Catalytic investigation on the titled complexes has been carried out on model reactions (asymmetric sulfoxidation and asymmetric oxidative-coupling reactions).

• 单位
  配位化学国家重点实验室; 南京大学