ChemInform Abstract: Extrusion of CO from Aryl Ketones: Rhodium(I)‐Catalyzed C—C Bond Cleavage Directed by a Pyridine Group.

作者：Zhi‐Quan Lei; Hu Li; Yang Li; Xi‐Sha Zhang; Kang Chen; Xin Wang; Jian Sun; Zhang‐Jie Shi

来源：ChemInform, 2012, 43(29): no-no.

DOI：10.1002/chin.201229089

• polyphenyl derivatives
• decarbonylation
• pyridine derivatives
• ketones (benzene compounds)

An anchimeric assistance of an N‐containing directing group, generally 2‐pyridyl is critical for the success of the double C—C cleavage process.

• 单位
  北京大学