Ruthenium(II)-Catalyzed Hydroamination of Allenoates: A Regioselective Synthesis of Allylamines

作者：Wang, Hua; Wang, He; Li, Lei; Wang, Xin; Sun, Ran; Zhou, Ming-Dong^*

来源：Advanced Synthesis & Catalysis, 2022, 364(23): 4152-4156.

DOI：10.1002/adsc.202200184

• Ruthenium(II) catalysis
• Hydroamination
• Allenoates
• Arylamines
• E-allylic amines

A ruthenium(II)-catalyzed hydroamination of allenoates with arylamines has been developed. This strategy provides an approach to synthesize E-allylic amines in good yields with high atom-economy and high levels of chemo-, regio- and E-selectivities with a broad substrate scope.

• 单位
  辽宁石油化工大学