末端含蓝光发色团的超支化聚苯材料的合成

作者：程格; 赵凌; 王跃川

来源：Acta Polymerica Sinica, 2005, (02): 285-288.

• 超支化聚苯
• 格氏试剂
• 二苯乙烯
• 二苯乙炔
• 蓝色发光 Hyperbranched polyphenylene
• Grignard
• Stilbenyl
• Diphenylacetylenyl
• Blue luminescence

One\|pot”reaction of 1,3,5 tribromobenzene with nonylmagnesium bromide,prepared by 1\|bromononane with magnesium in THF,catalyzed by Ni(PPh\-3)\-2Cl\-2,was used to obtain hyperbranched polyphenylene 1.The macromolecule was characterized by GPC with molecular weight M n=4247 and polydispersity ...

• 单位
  高分子材料工程国家重点实验室; 四川大学