Assembling of a novel 3D Ag(Ⅰ)-MOFs with mixed ligands tactics:Syntheses, crystal structure and catalytic degradation of nitrophenol

作者：Dandan Huang; Xueqian Wua; Junwu Tian; Xiaokun Wang; Zhihang Zhou; Dongsheng Li

来源：Chinese Chemical Letters, 2018, 29(06): 845-848.

A silver-based metal-organic framework(Ag-MOFs), [Ag2(H3 ddcba)(dpp)2](1)(H5 ddcba = 3,5-(di(2’,5’-dicarboxylphenyl)benozoic acid, dpp = 1,3-di(4-pyridyl)propane), was successfully constructed via hydrothermal assembly of a pentacaboxylate ligand, a N-donor ligand and Ag(I) ions, which possesses a pcu topology and exhibits excellent catalytic properties in aqueous solution for the degradation of onitrophenol(2-NP), m-nitrophenol(3-NP) and p-nitrophenol(4-NP). Related kinetics of such catalytic reactions, photoluminescent and thermal stability of compound 1 were also investigated.

• 单位
  结构化学国家重点实验室; 三峡大学