Dichloridobis(1,3-diisopropyl-4,5-dimethyl-1H-imidazol-3-ium-2-thiolate-百S)copper(II)

作者：Ulrich Flrke; Aziza Ahmida; Jrg Schrder; Hans Egold

来源：Acta Crystallographica Section E-Structure Reports Online, 2013, 69(4): m211-m211.

DOI：10.1107/s1600536813006879

The molecular structure of the title compound, [CuCl2(C11H20N2S)2], shows the CuII atom with a distorted tetrahedral geometry from two Cl atoms [Cu〞Cl = 2.2182 (6) ] and two thione S atoms [Cu〞S = 2.3199 (6) ]. The angles at the copper cation, which lies on a twofold rotation axis, are Cl〞Cu〞Cl = 142.84 (4)～, Cl〞Cu〞S = 94.80 (2) and 99.97 (2)～, and S〞Cu〞S = 132.46 (4)～. The planes of the two imidazolium rings make a dihedral angle of 76.92 (8)～.