Synthesis and Crystal Structure of a Ruthenium(Ⅱ) Compound of Dinitrogen

作者：阚剑; 张礼仪; 文惠敏; 施林熙; **宁

来源：结构化学, 2008, (10): 1167-1170.

DOI：10.14102/j.cnki.0254-5861.2008.10.005

• crystal structure
• dinitrogen
• ruthenium crystal structure
• dinitrogen
• ruthenium

The title compound Ru(bph)(PPh3)2(N2)·(PF6)·1.5CH2Cl2(bph=N-(benzoyl)-N′-(picolinylidene)-hydrazine) has been prepared and characterized by X-ray diffraction analysis.It crystallizes in the monoclinic system=space group P21/n with a=13.5201(6)=b=15.5078(6)=c=25.0656(13)=β=100.257(3)°=C50.50H43Cl3F6...

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