[米-N1,N2-Bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidato]bis[chloridocopper(II)]

作者：Yang Liu; Bingguang Zhang; Kejian Deng

来源：Acta Crystallographica Section E-Structure Reports Online, 2013, 69(1): m45-m45.

DOI：10.1107/s1600536812048659

The binuclear title compound, [Cu2(C12H10N6S2)Cl2], possesses twofold rotational symmetry. The CuII atom occupies a four-coordinate pseudo-tetrahedral environment bound to one S atom, one imine N atom and one pyridine N atom from the N1,N2-bis(pyridin-2-yl)hydrazine-1,2-dicarbothioamidate ligand, and one Cl anion. The metal atoms are connected via the bis-tridentate ligand into a binuclear structure. The molecule is bow-shaped with the pyridine rings inclined to one another by 51.56 (14)～. In the crystal, N〞H...Cl hydrogen bonds lead to the formation of ribbons propagating along [001]. These ribbons are connected via C〞H...Cl, C〞H...S and 羽每羽 interactions [centroid每centroid distance = 3.6146 (19) ], leading to the formation of a three-dimensional structure.