A Phenylene‐Bridged Cyclohexa‐ meta ‐phenylene as Hexa‐ peri ‐hexabenzocoronene Precursor

作者：Bastian Dumslaff; Dr Manfred Wagner; Dr Dieter Schollmeyer; Dr Akimitsu Narita; Prof Dr Klaus Müllen

来源：Chemistry – A European Journal, 2018, 24(46): 11908-11910.

DOI：10.1002/chem.201801949

• Fused ring systems
• Hydrocarbons
• Macrocycles
• Polyphenylenes
• Synthesis design

Abstract(#br)A phenylene‐bridged cyclohexa‐ meta ‐phenylene was synthesized via intramolecular Yamamoto coupling of an appropriate p ‐quinquephenyl derivative carrying four m ‐chlorophenyl substituents. The structural proof could be obtained by single‐crystal X‐ray diffraction analysis, which also r...