Aerobic Oxidation of 5‐(Hydroxymethyl)furfural Cyclic Acetal Enables Selective Furan‐2,5‐dicarboxylic Acid Formation with CeO2‐Supported Gold Catalyst

作者:Dr. Minjune Kim; Yaqiong Su; Prof. Atsushi Fukuoka; Prof. Dr. Emiel J. M. Hensen; Dr. Kiyotaka Nakajima
来源:Angewandte Chemie, 2018, 130(27): 8367-8371.
DOI:10.1002/ange.201805457文章关键词:Acetale,Biomasse,Gold,Heterogene Katalyse,Tr?gerkatalysatoren原文摘要:The ut

摘要

The utilization of 5‐(hydroxymethyl)furfural (HMF) for the large‐scale production of essential chemicals has been largely limited by the formation of solid humin as a byproduct, which prevents the operation of stepwise batch‐type and continuous flow‐type processes. The reaction of HMF with 1,3‐propa...