石煤提钒酸浸液萃取预处理的研究

作者:黄晶; 张一敏; 刘涛; 王一; 王非
来源:中国工程院化工、冶金与材料工程学部第九届学术会议, 徐州, 2012-10-06.

摘要

  During the process of blank roasting-acid leaching-pretreatment-extraction in vanadium extraction from stone coal, the pH value of acid leaching solution is ca.0.5 and many unwanted ions are involved in it, hence, it can not be used directly for vanadium extraction.The acid leaching solution should be reduced by Na2 SO3 and adjusted pH by CaO for further vanadium extraction.Experimental results showed that when the nNa2so3 ∶ nTFe =1 ∶ 1, most Fe3+ can be reduced which is beneficial to the vanadium extraction, and the consumption of CaO can be reduced by 42%, the one stage extraction rate can increased by 23%.

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