C―H Activation

作者:LI Chao-Jun
来源:Acta Physico - Chimica Sinica, 2019, 35(09): 905.
DOI:10.3866/pku.whxb201903057

摘要

<正>Conventional syntheses of organic chemicals rely mostly on reactions between various reactive functional groups and reagents. Mechanistically, they are dominated by the involvement of highly reactive intermediates such as carbocations, carbanions, radicals and carbenes. Due to the high dissociation energy and low acidity of common C―H bonds,