科研之友
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摘要
SnS with high theoretical capacity is a promising anode material for lithium‐ion batteries. However, dramatic volume changes of SnS during repeated discharge/charge cycles result in fractures or even pulverization of electrode, leading to rapid capacity degradation. To solve this problem, we construct a dual‐carbon‐confined SnS nanostructure (denoted as SnS@C/rGO) by depositing semi‐graphitized carbon layers on reduced graphene oxide (rGO) supported SnS nanoplates during high‐temperature reduction. The dual carbon of rGO and in?situ formed carbon coating confines growth of SnS during the high‐temperature calcination. Moreover, during the reversible Li+ storage the dual‐carbon modification enables good electronic conductivity, relieves the volume effect, and provides double insurance for the electrical contact of SnS even after repeated cycles. Benefiting from the dual‐carbon confinement, SnS@C/rGO exhibits significantly enhanced rate capability and cycling stability compared with the bare and single carbon modified SnS. SnS@C/rGO presents reversible capacity of 1029.8?mAh?g?1 at 0.2?A?g?1. Even at a high current density of 1?A?g?1, it initially delivers reversible capacity of 934.0?mAh?g?1 and retains 98.2% of the capacity (918.0?mAh?g?1) after 330 cycles. This work demonstrates potential application of dual‐carbon modification in the development of electrode materials for high‐performance lithium‐ion batteries.(#br)Dual carbon of rGO and in?situ formed carbon coating confines growth of SnS in the high‐temperature calcination and relieves the volume effect during the reversible Li+ storage. The dual‐carbon modification enables stable cyclic performance of SnS.
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