Adsorption of U(Ⅵ) from acid solution on a low-cost sorbent:equilibrium, kinetic, and thermodynamic assessments

作者：Mohamed F.Cheira^*; Hamed I.Mira; Ahmed K.Sakr; Saad A.Mohamed

来源：Nuclear Science and Techniques, 2019, 30(10): 126-143.

In this paper, waste clay was cured with ethyl acetate to obtain treated clay(TC), which was modified with gallic acid to obtain a low-cost sorbent that was characterized by EDX, SEM, and FTIR analysis. Uranium(Ⅵ) adsorption was achieved using the batch adsorption method on the TC and gallic acid-modified treated clay(GMTC). The maximum uptakes of U(Ⅵ) on TC and GMTC were 37.2 and 193.0 mg/g, respectively.The U(Ⅵ) adsorption kinetics on the TC and GMTC sorbents were well-fitted by the pseudo-second-order mechanism, and the adsorption equilibrium followed the Langmuir model. The optimum parameters were applied to El Sela leach solution for uranium recovery.