Elusive Antimony‐Centered Radical Cations: Isolation, Characterization, Crystal Structures, and Reactivity Studies

作者：Tao Li; Houjia Wei; Yong Fang; Lei Wang; Sheng Chen; Dr Zaichao Zhang; Dr Yue Zhao; Dr Gengwen Tan; Prof Dr Xinping Wang

来源：Angewandte Chemie, 2017, 129(2): 647-651.

DOI：10.1002/ange.201610334

• Antimon
• Dichtefunktionalrechnungen
• EPR-Spektroskopie
• Radikalkationen
• Stibine

Abstract(#br)One‐electron oxidation of the stibines Aryl3Sb ( 1 , Aryl=2,6‐ i Pr2‐4‐OMe‐C6H2; 2 , Aryl=2,4,6‐ i Pr3‐C6H2) with AgSbF6 and NaBArylF4 (ArylF=3,...

• 单位
  现代配位化学国家重点实验室; 南京大学