Synthesis and Structure of a Mn(Ⅱ)-triazolyl Coordination Polymer Consisting of Dinuclear Units

作者：吴涛; 许红岩; 孔凡振; 郁章玉; 王瑞虎

来源：结构化学, 2012, 31(11): 1557-1562.

DOI：10.14102/j.cnki.0254-5861.2012.11.005

• crystal structure
• energetic compounds
• manganese
• triazolyl crystal structure
• energetic compounds
• manganese
• triazolyl

The reaction of bis(1,2,4-triazolyl-4-yl) (btr) and MnClO4·6H2O gave rise to a Mn(Ⅱ) complex comprised of unprecedented dinuclear Mn(Ⅱ) units, {[Mn2(btr)3(H2O)5]-(ClO4)4(H2O)2]n(1). Single-crystal X-ray diffraction analysis revealed that 1 crystallizes in the monoclinic space group C2/c. btr adopts ...

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