光催化下(-)-马鞭烯酮的重排

作者：宋志光; 李叶芝; 黄化民

来源：高等学校化学学报, 2004, (11): 2119-2121.

• -)-α-蒎烯
• (-)-马鞭烯酮
• (-)-异菊花烯酮 Pinene
• (-)-Verbenone
• (-)-Isochrysanthenone

We reported a facile synthesis of (-)-isochrysanthenone(2) from (-)-α-pinene in a high yield. When (-)-α-pinene reacted with O 2 in the presence of Co[4-Me(C 5H 4N) 2]Br 2 used as a catalyst, the crude product of (-)-verbenone(1) was formed, and the crude product 1 was directly irradiated with ...