Guanidinium Perfluoridotitanate(IV) Compounds: Structural Determination of an Oligomeric [Ti6F27]3– Anion, and an Example of a Mixed‐Anion Salt Containing Two Different Fluoridotitanate(IV) Anions

作者：Igor M Shlyapnikov; Evgeny A Goreshnik; Zoran Mazej

来源：European Journal of Inorganic Chemistry, 2018, 2018(48): 5246-5257.

DOI：10.1002/ejic.201801207

• Guanidine
• Titanium
• Crystal structure
• Fluorides
• Hybrid compounds

Chemical reactions between guanidinium carbonate or guanidinium chloride and titanium tetrafluoride in anhydrous hydrogen fluoride (aHF) were studied. The obtained products were recrystallized from saturated HF, SO2 and CH3CN solutions. Single‐crystal growths resulted in the de...