Bis{2-bromo-4-chloro-6-[(E)-(2,6-dimethylphenyl)iminomethyl]phenolato-百2N,O}cobalt(II)

作者:Gang Zhu; Bao Juan Jiao
来源:Acta Crystallographica Section E-Structure Reports Online, 2013.
DOI:10.1107/s1600536813003747

摘要

In the title complex, [Co(C15H12BrClNO)2], the CoII ion is coordinated by two N,O-bidentate 2-bromo-4-chloro-6-[(E)-(2,6-dimethylphenyl)iminomethyl]phenolate ligands, generating a squashed CoN2O2 tetrahedral coordination geometry. The dihedral angles between the aromatic rings in the ligands are 82.60 (14) and 71.79 (14)~. The complex has approximate local noncrystallographic twofold symmetry. In the crystal, weak aromatic 羽每羽 stacking is observed [centroid每centroid separation = 3.6434 (18) ].

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