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摘要
The natural alkaloid isoanabasine was prepared by catalytic hydrogenation of tetrahydrobipyridines with (S)-BINAP-Rh complex. The tetrahydrobipyridines bearing bigger N-substituted group displayed high (stereoselectivity) and low reaction rate. Moreover, the position of the double bond on piperidine...
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单位中国科学院长春应用化学研究所; 高分子物理与化学国家重点实验室; 中国科学院研究生院
