cis-Dichlorido(dimethyl sulfoxide-百S)(N,N,N∩,N∩-tetramethylguanidine-百N∩∩)platinum(II)

作者：Ivan I Eliseev; Nadezhda A Bokach; Matti Haukka; Irina A Golenya

来源：Acta Crystallographica Section E-Structure Reports Online, 2013, 69(2): m117-m118.

DOI：10.1107/s160053681300130x

In the title compound, cis-[PtCl2(C5H13N3)(C2H6OS)], the four-coordinate PtII atom is bonded to one N atom of the N,N,N∩,N∩-tetramethylguanidine ligand, one dimethyl sulfoxide S atom and two chloride ligands, forming a cis-square-planar geometry. The bond lengths and angles of the N〞Pt〞Cl functionality are typical for imine dichloridoplatinum(II) complexes. The H atom of the imino group is oriented towards the O atom of the sulfoxide group of a neighboring molecule and forms an N〞H...O hydrogen bond.