环己酮与丙烯酸甲酯及(S)-3-(2′-氧环己基)-丙酸与醇的酯化反应

作者：王会萍; 商艳梅; 王磊; 李叶芝; 黄化民

来源：高等学校化学学报, 2006, (05): 894-896.

• Fe2(SO4)3·xH2O
• 光活性3-(2′-氧环己基)-丙酸甲酯
• 光活性3-(2′-氧环己基)-丙酸乙酯
• 光活性3-(2′-氧环己基)-丙酸丁酯
• (R)-四氢噻唑-2-硫酮-4-羧酸钾盐 Fe_(2)(SO_(4))_3·xH_(2)O
• Optically active methyl-3-(2′-oxocyclohexyl)-propionate
• Optically active ethyl-3-(2′-oxocyclohexyl)propionate
• Optically active n-butyl-3-2′-oxocy-clohexyl)propionate
• (R)-potassium thiazolidine-2-thione-4-carboxylate

The esterification of carboxylic acid with alcohol in the presence of catalytic amounts of mineral acids is one of the most methods for preparing esters.The catalysts generally preferred are sulfuric acid or p-toluenesulfonic acid.But the products esters were racemic when(S)-3-(2′-oxocyclohexyl) pro...

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